Celecoxib Catalyzed the Coupling Reaction of Epoxide and CO2

被引:0
|
作者
Wu, Ling [1 ]
Xia, Xiaocheng [1 ]
An, Wenying [1 ]
Cui, Wenshan [1 ]
Liu, Yue [1 ]
Lv, Wei [1 ]
Wu, Fengtian [1 ]
机构
[1] East China Univ Technol, Jiangxi Prov Key Lab Polymer Micro Nano Mfg & Devi, Nanchang 330013, Peoples R China
关键词
Carbon dioxide; epoxide; cyclic carbonate; TBAB; celecoxib; benzoic acid; CARBON-DIOXIDE; CYCLIC CARBONATES; ORGANOCATALYSTS; CONVERSION;
D O I
10.2174/0115701786276731231206113215
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this study, high yields of various cyclic carbonates are obtained by employing the drug celecoxib to promote the coupling reaction of CO2 and epoxide using tetrabutylammonium bromide. This strategy enables the synthesis of benzoic acid, phenylpropiolic acid, and 2, 4-quinazolinedione. In addition, the model reaction mechanism is proposed.
引用
收藏
页码:611 / 619
页数:9
相关论文
共 50 条
  • [1] Reaction parameters dependence of the CO2/epoxide coupling reaction catalyzed by tunable ionic liquids, optimization of comonomer-alternating enhancement pathway
    Pawar, Atul A.
    Kim, Hern
    JOURNAL OF CO2 UTILIZATION, 2019, 33 : 500 - 512
  • [2] Reaction Mechanism of Epoxide Cycloaddition to CO2 Catalyzed by Salen-M (M = Co, Al, Zn)
    Wang, Ting-Ting
    Xie, Yong
    Deng, Wei-Qiao
    JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (39): : 9239 - 9243
  • [3] A bimetallic iron(III) catalyst for CO2/epoxide coupling
    Buchard, Antoine
    Kember, Michael R.
    Sandeman, Karl G.
    Williams, Charlotte K.
    CHEMICAL COMMUNICATIONS, 2011, 47 (01) : 212 - 214
  • [4] Influence of Pore Size on Cycloaddition Reaction of CO2 and Epoxide Catalyzed by Supported Imidazolium Ionic Liquids
    Yu, Xiaohan
    Zhang, Ruiyu
    Sun, Xinyi
    Liu, Yi
    CHEMICAL ENGINEERING & TECHNOLOGY, 2025, 48 (01)
  • [5] Bifunctional Metalloporphyrins-Catalyzed Coupling Reaction of Epoxides and CO2 to Cyclic Carbonates
    Bai Dongsheng
    Wang Xiaoxuan
    Song Yingying
    Li Bo
    Zhang Lilong
    Yan Peng
    Jing Huanwang
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (02) : 176 - 180
  • [6] Bifunctional Metalloporphyrins-Catalyzed Coupling Reaction of Epoxides and CO2 to Cyclic Carbonates
    BAI, Dongsheng
    WANG, Xiaoxuan
    SONG, Yingying
    LI, Bo
    ZHANG, Lilong
    YAN, Peng
    JING, Huanwang
    Chinese Journal of Catalysis, 2010, 31 (02): : 176 - 180
  • [7] MECHANISTIC ASPECTS OF CO2 EPOXIDE COUPLING REACTIONS - FORMATION OF POLYCARBONATES
    DARENSBOURG, DJ
    HOLTCAMP, MW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 296 - INOR
  • [8] Azaboratrane as an exceptionally potential organocatalyst for the activation of CO2 and coupling with epoxide
    Faizan, Mohmmad
    Srivastav, Nikhil
    Pawar, Ravinder
    MOLECULAR CATALYSIS, 2022, 521
  • [9] Catalytic Coupling of CO2 with Epoxide Over Supported and Unsupported Amines
    Yu, K. M. Kerry
    Curcic, Igor
    Gabriel, Joseph
    Morganstewart, Henry
    Tsang, Shik Chi
    JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (11): : 3863 - 3872
  • [10] CO2(CO)8 CATALYZED REACTION OF OXETANES WITH TRIALKYLSILANES
    KANG, KT
    WEBER, WP
    TETRAHEDRON LETTERS, 1985, 26 (47) : 5753 - 5754