A novel naphthalene diimide-based compound:synthesis, photochromism, ammonia vapor and triethylamine detection

被引：0

作者：

Mao, Yuling ^{[1
]}

Shan, Boyu ^{[1
]}

Yu, Jia ^{[1
]}

Liu, Xinxin ^{[1
]}

Chu, Jingying ^{[1
]}

Ma, Xinyue ^{[1
]}

Li, Miao ^{[1
]}

Zheng, Yimeng ^{[1
]}

Zhu, Baili ^{[1
]}

Zuo, Minghui ^{[1
]}

Cui, Shuxin ^{[1
]}

机构：

[1] Mudanjiang Normal Univ Mudanjiang, Coll Chem & Chem Engn, Heilongjiang Key Lab Photoelect Funct Mat, Mudanjiang 157011, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2024年 / 338卷

关键词：

Photochromism; Naphthalimide; Ammonia sense; Triethylamine detection; METAL-ORGANIC FRAMEWORK; COORDINATION; POLYMERS; IMPACT; PI;

D O I：

10.1016/j.jssc.2024.124902

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel naphthalene diimide-based compound, designated as [Zn(BINDI)0.25 & sdot;(C2H5NO)]n (1), has been successfully synthesized under solvothermal conditions, utilizing N, N '-bis(5-isophthalic acid) naphthalenediimide (H4BINDI) and Zn(NO3)2 & sdot;6H2O as raw materials. Single crystal X-ray diffraction analysis revealed that compound 1 forms a 3D structure, with BINDI4- and C2H5NO- serving as organic ligands and Zn(II) as the center metal ion. Notably, upon exposure to a 300 W xenon lamp, compound 1 rapidly transitions from orange to dark blue within 5 s. Furthermore, as the duration of irradiation increases, 1 exhibits photocontrolled fluorescence properties. Additionally, it possesses the capability to detect ammonia vapor and triethylamine.

引用

页数：7

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