Impact of halogen⋯halogen interaction on the mechanical motion of a 3D Pb(II) coordination polymer of elusive topology

被引：0

作者：

Khan, Samim ^{[1
]}

Naaz, Sanobar ^{[1
]}

Ahmad, Shamim ^{[2
]}

Gomila, Rosa M. ^{[3
]}

Chanthapally, Anjana ^{[4
]}

Frontera, Antonio ^{[3
]}

Mir, Mohammad Hedayetullah ^{[1
]}

机构：

[1] Aliah Univ, Dept Chem, Kolkata 700156, India

[2] Indian Inst Sci Educ & Res IISER Kolkata, Dept Chem Sci, Mohanpur Campus, Mohanpur 741246, India

[3] Univ Illes Balears, Dept Quim, Crta Valldemossa km 7-5, Palma De Mallorca 07122, Baleares, Spain

[4] Mar Athanasius Coll Engn, Dept Sci, Kothamangalam, Kerala, India

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 75期

关键词：

MOLECULAR-CRYSTALS; CHEMISTRY; LIGHT;

D O I：

10.1039/d4cc03746d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report the synthesis of a Pb(ii) based three-dimensional coordination polymer (3D CP), [Pb(DCTP)](n) (1) [H2DCTP = 2,5-dichloroterephthalic acid] with an unprecedented topology, which exhibits a photomechanical effect wherein crystals show jumping upon UV irradiation. The Pb(ii) CP forms a type II Cl & ctdot;Cl interaction, which weakens further upon UV irradiation to resolve the anisotropic mechanical strain. The work presented here could be a beacon to the nascent field of photoactuating smart materials.

引用

页码：10370 / 10373

页数：4

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