Revolutionizing dye removal: g-C3N4-Modified ZnO nanocomposite for exceptional adsorption of basic fuchsin dye

被引:4
|
作者
Khezami, Lotfi [1 ]
Bessadok, Abdelbaset [2 ]
Ben Aissa, Mohamed Ali [3 ]
Ahmed, Amani H. [4 ]
Modwi, A. [3 ]
Benhamadi, Naoufel [1 ]
Assadi, Aymen Amine [5 ,6 ]
机构
[1] Imam Mohammad Ibn Saud Islamic Univ IMSIU, Coll Sci, Dept Chem, POB 5701, Riyadh 11623, Saudi Arabia
[2] King Saud Univ, Coll Engn, Chem Engn Dept, POB 800, Riyadh 11421, Saudi Arabia
[3] Qassim Univ, Coll Sci, Dept Chem, POB 6644, Buraydah 51452, Saudi Arabia
[4] Majmaah Univ, Coll Sci, Dept Chem, PO 66, Al Majmaah 11952, Saudi Arabia
[5] Imam Mohammad Ibn Saud Islamic Univ, Coll Engn, Riyadh 11432, Saudi Arabia
[6] Univ Rennes, ENSCR, 11 Allee Beaulieu, F-35708 Rennes, France
关键词
g-C 3 N 4 @ZnO nanosorbent; BF dye; Adsorption capacity; pH; Freundlich isotherm; CONGO RED-DYE; AQUEOUS-SOLUTION; NANOPARTICLES; COMPOSITES; ADSORBENT; WATER;
D O I
10.1016/j.inoche.2024.112413
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Organic dye pollution poses a critical environmental challenge, necessitating sustainable solutions for effective removal. This study presents a g-C3N4-modified ZnO nanosorbent to remove Basic Fuchsin dye from aqueous solutions efficiently. Synthesis and comprehensive characterization (SEM, BET, XPS, FTIR, XRD) elucidated the nanosorbent's properties and adsorption performance and mechanisms. Experimental results demonstrate optimal performance under alkaline conditions, with significant adsorption capacity (up to 478.14 mg/g at 300 ppm dye concentration). Adsorption behavior is well-described by the Freundlich isotherm and pseudo-firstorder kinetic models. The nanosorbent demonstrates reusability and cost-effectiveness and exploits hydrogen bonding and 7C-7C interactions for adsorption. This work highlights the potential of g-C3N4@ZnO as a promising solution for mitigating dye pollution and promoting sustainable water treatment technologies.
引用
收藏
页数:12
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