Recent Advances in Gold-Catalyzed Transformations of Vinyldiazo Reagents

被引:0
|
作者
Bernardo, Olaya [2 ]
Garcia-Martinez, Patricia
Santamaria, Javier
Lopez, Luis A. [1 ]
机构
[1] Univ Oviedo, Inst Univ Quim Organomet Enrique Moles, Dept Quim Organ & Inorgan, Julian Claveria 8, Oviedo 33006, Spain
[2] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
来源
SYNTHESIS-STUTTGART | 2024年 / 56卷 / 24期
关键词
vinyldiazo compounds; gold; carbenes; cyclization; C-H functionalization; regioselectivity; ALPHA-DIAZOCARBONYL COMPOUNDS; CYCLOADDITION REACTIONS; VINYLOGOUS REACTIVITY; INTERMOLECULAR 2+2; DIAZO DERIVATIVES; N-ALLENAMIDES; ACTIVATION; FUNCTIONALIZATION; CYCLOPROPENATION; INSERTIONS;
D O I
10.1055/a-2343-1001
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Since their discovery in 2011, gold-catalyzed transformations of vinyldiazo compounds have become an important synthetic tool, enabling the identification of new reaction patterns that have greatly expanded the versatility of these reagents. In this short review, we showcase the most relevant advances that have been made in this exciting area of research.
引用
收藏
页码:3728 / 3740
页数:13
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