Visible-Light-Induced Synthesis of Vinyl Sulfones via Decarboxylative Sulfonylation of Cinnamic Acids Using Sulfonylazides/p-Toluenesulfonylmethyl Isocyanide/β-Keto Sulfones

被引：0
|
作者：
Ishu, Km [1 ]
Kumar, Mahesh [1 ]
Singh, Krishna Nand [1 ]
机构：
[1] Banaras Hindu Univ, Inst Sci, Dept Chem, Varanasi 221005, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 15期
关键词：
C-S; AEROBIC DIFUNCTIONALIZATION; STEREOSELECTIVE-SYNTHESIS; CATALYZED SULFONYLATION; TOSYLMETHYL ISOCYANIDE; RADICAL-ADDITION; FUNCTIONALIZATION; PHOTOREDOX; DERIVATIVES; ALKENES;
D O I：
10.1021/acs.joc.4c01252
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient visible-light-induced synthesis of vinyl sulfones has been accomplished via decarboxylative sulfonylation of cinnamic acids using sulfonylazides, p-toluenesulfonylmethyl isocyanide, and beta-keto sulfones as sulfonyl source, in the presence of inexpensive organic photocatalysts like rhodamine B and eosin Y. The reaction is facile, straightforward, and endowed with wide substrate scope and functional group tolerability.
引用
收藏
页码：10919 / 10928
页数：10
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