Manganese-catalyzed C-C and C-N bond formation with alcohols via borrowing hydrogen or hydrogen auto-transfer

被引：0
|
作者：
Ansari, Mohd Farhan [1 ]
Maurya, Atul Kumar [1 ]
Kumar, Abhishek [1 ]
Elangovan, Saravanakumar [1 ]
机构：
[1] Indian Inst Technol BHU, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 20卷
关键词：
alcohols; alkylation; amines; borrowing hydrogen; hydrogen auto-transfer; manganese; CROSS-COUPLING REACTIONS; ALPHA-ALKYLATION; SECONDARY ALCOHOLS; KETONES; AMINES; DEHYDROGENATION; CYCLOALKANES; AMINATION; ALDEHYDES; NITRILES;
D O I：
10.3762/bjoc.20.98
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Transition -metal -mediated "borrowing hydrogen" also known as hydrogen auto -transfer reactions allow the sustainable construction of C-C and C-N bonds using alcohols as hydrogen donors. In recent years, manganese complexes have been explored as efficient catalysts in these reactions. This review highlights the significant progress made in manganese -catalyzed C-C and C-N bondformation reactions via hydrogen auto -transfer, emphasizing the importance of this methodology and manganese catalysts in sustainable synthesis strategies.
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收藏
页码：1111 / 1166
页数：56
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