Silver-Catalyzed Decarboxylative Nitrooxylation of Aliphatic Carboxylic Acids

被引：0

作者：

Yu, Qian ^{[1
]}

Zhou, Donglin ^{[1
]}

Yu, Pingping ^{[1
]}

Song, Chunlan ^{[1
]}

Tan, Ze ^{[1
]}

Li, Jiakun ^{[1
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 27期

基金：

中国国家自然科学基金;

关键词：

ANODIC-OXIDATION; MALONIC-ACID; NITRATE; ELECTROLYSIS; CHEMISTRY; RADICALS; ELECTROCHEMISTRY;

D O I：

10.1021/acs.orglett.4c02180

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here, we present a silver-catalyzed decarboxylative nitrooxylation via a radical-based approach. The substrate scope of this reaction prototype extends to nonactivated primary and secondary carboxylic acids. This protocol provides a practical method for the synthesis of an unprecedented family of organic nitrates and exhibits wide functional group compatibility. Preliminary mechanistic studies reveal that a high-valent silver(II) nitrate complex is a versatile NO3 resource pool, allowing for facile C-O bond formation.

引用

页码：5856 / 5861

页数：6

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