Visible Light Photoredox-Catalyzed Formyl/Carboxylation of Activated Alkenes with Glyoxylic Acid Acetals and CO2

被引：7
|
作者：
Yang, Han [1 ]
Yao, Yang [1 ]
Yang, Qi [1 ]
Yao, Yingming [2 ]
Sun, Jianwei [1 ,3 ]
Sun, Song [1 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Dushu Lake Campus, Suzhou 215123, Peoples R China
[3] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong 999077, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 20期
基金：
中国国家自然科学基金;
关键词：
AMINO-ACIDS; STYRENES; CARBOXYLATION; DICARBOFUNCTIONALIZATION; HYDROFORMYLATION;
D O I：
10.1021/acs.orglett.4c00841
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A photoredox-catalyzed sequential alpha-formyl/carboxylation of alkenes with glyoxylic acid acetals and CO2 has been developed to afford a range of masked gamma-formyl esters in good yields, which could be readily transformed into diverse compounds, such as gamma-formyl ester, hemiacetal, and 1,4-diol. This reaction features mild conditions, readily available starting materials, and operational simplicity.
引用
收藏
页码：4194 / 4199
页数：6
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