This study examines the relationship between Land Surface Temperature (LST) and Land Use and Land Cover (LULC) through a combination of ground-based, satellite-based, and re-analytical products. It focuses on the most recent changes in land surface temperature between 1991 and 2021 in the Chalisgaon Taluka of Maharashtra State, India. The results demonstrate that LULC changes have a significant impact on the climate through a range of mechanisms. There appears to be a connection between the changes in LULC spatial pattern with change in LST and Normalised Difference Vegetation Index (NDVI). The error matrix is calculated for the assessment of the accuracy of classified land use land cover images. This analysis confirms that the most substantial alterations are related to changes in plant cover, as reflected by the alterations in LULC classes as well as in NDVI. The Built-up area covered 0.91% in 1991, but grew to 6.48% in 2021 compared to 1991. Between 1991 and 2021, the study region's vegetation and agricultural land area declined by 2.64%. It was discovered that there has been a quick transition from vegetation to built-up area. The mean LST ranges were amplified dramatically from 35.05 0 C to 46.22 0 C from 1991 to 2021, largely due to the growing build-up zone and decrease vegetation The study found that the growth of urban landscapes and associated rise in human activities, as well as shifting of agricultural patterns, LULC related changes to surface temperature, and regional climate feedback across this region, warrants further research. The finding of the present study will be useful for city planner and developers as baseline information for achieving the sustainable development of the area.