Influence of chemical treatment and interaction with matrix on room temperature phosphorescence of carbon dots

In this work, composite materials were formed based on various matrices (polymer and porous cellulose matrix) and carbon dots (CDs) with intense room-temperature phosphorescence (RTP). The effect of post-synthesis chemical treatment with citric acid or urea on the optical properties of composites was studied: the increase in carboxy and carbonyl groups led to an increase of RTP signals that could be seen with the naked eye over several seconds. The fabricated composites demonstrated good stability and reversibility of RTP signals by mild heating. Based on the developed CDs, luminescent inks were used for a simple demonstration of the data encryption on paper.