Transformation of furfural into dimorpholinocyclopentenone using Al-SBA-15 materials

被引：1
|
作者：
Fernandez, Miriam Lopez [1 ]
Len, Thomas [1 ]
Urbano, Juan [2 ,3 ]
Balu, Alina [1 ]
Luque, Rafael [4 ,5 ]
机构：
[1] Univ Cordoba, Dept Quim Organ, Inst Quim Fina & Nanoquim, Campus Rabanales,Edificio Marie Curie C-3,Ctra Nna, E-14014 Cordoba, Spain
[2] Univ Huelva, Lab Sustainable & Circular Technol CIDERTA, Fac Expt Sci, Campus El Carmen, Huelva 21071, Spain
[3] Univ Huelva, Fac Expt Sci, Chem Dept, Campus El Carmen, Huelva 21071, Spain
[4] Natl Univ Sci & Technol Polytehn Bucharest, 1-7 Gheorghe Polizu Str, Bucharest, Romania
[5] Univ ECOTEC, Km 13-5 Samborondon,EC092302, Samborondon, Ecuador
来源：
SUSTAINABLE CHEMISTRY AND PHARMACY | 2024年 / 39卷
关键词：
Furfural; Morpholine; Cyclopentenone; Al-SBA-15; Cyclization rearrangement; CATALYTIC-PROPERTIES; SBA-15; SILICA; CYCLOPENTENONE DERIVATIVES; ACID; REARRANGEMENT; CYCLOPENTANONE; HYDROGENATION; CONVERSION; DEHYDRATION; ALCOHOL;
D O I：
10.1016/j.scp.2024.101573
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dimorpholinocyclopentenone, being a relevant chemical compound widespread employed in the pharmaceutical industry, can be synthesized by a facile chemically catalyzed conversion reaction between furfural and morpholine. This reaction was investigated in this work by employing a simple, affordable non -noble metal mesoporous Al -SBA -15 with improved catalytic activity and superior product selectivity. The prepared materials shown a mesoporous structure with high pore volume and enlarged surface area, which are impacted by the quantity of aluminium atom incorporated. These differences leading to superior catalytic properties of Al -SBA -15 with a Si/Al ratio of 10.
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页数：8
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