Bound-State Relativistic Quantum Electrodynamics: A Perspective for Precision Physics with Atoms and Molecules

被引:4
|
作者
Nonn, Adam [1 ]
Margocsy, Adam [1 ]
Matyus, Edit [1 ]
机构
[1] Eotvos Lorand Univ, Inst Chem, ELTE, H-1117 Budapest, Hungary
基金
欧洲研究理事会;
关键词
ENERGY-LEVELS; ELECTRON; HELIUM; FOUNDATIONS; EQUATION;
D O I
10.1021/acs.jctc.4c00128
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Precision physics aims to use atoms and molecules to test and develop the fundamental theory of matter, possibly beyond the Standard Model. Most of the atomic and molecular phenomena are described by the quantum electrodynamics (QED) sector of the Standard Model. Do we have the computational tools, algorithms, and practical equations for the most possible complete computation of atoms and molecules within the QED sector? What is the fundamental equation to start with? Is it still Schrodinger's wave equation for molecular matter, or is there anything beyond that? This paper provides a concise overview of the relativistic QED framework and recent numerical developments targeting precision physics and spectroscopy applications with common features of the robust and successful relativistic quantum chemistry methodology.
引用
收藏
页码:4385 / 4395
页数:11
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