Fast-charging aqueous batteries enabled by a three-dimensional ordered Zn anode at deliberate concentration polarization

被引：0
|
作者：
Li, Jinze [1 ,2 ]
Mao, Eryang [3 ]
Ye, Xiaozhou [4 ]
Xu, Tian [2 ]
Zheng, Jie [2 ]
Xiao, Kaiwen [2 ]
Sun, Bingbing [2 ]
Ge, Ming [2 ]
Yuan, Xiaolei [2 ]
Cai, Zhao [1 ]
机构：
[1] China Univ Geosci, Fac Mat Sci & Chem, Wuhan 430074, Peoples R China
[2] Nantong Univ, Sch Chem & Chem Engn, Nantong 226019, Peoples R China
[3] Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[4] Shanghai Inst Satellite Engn, Res Dept 2, Shanghai 201109, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 58期
基金：
中国国家自然科学基金;
关键词：
23;
D O I：
10.1039/d4cc01798f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A finely controlled concentration polarization environment was deliberately created to fabricate a three-dimensional ordered Zn metal anode with (002)-dominated planes, which enabled a high-rate aqueous Ni-Zn pouch cell with a high discharge capacity of 187.3 mA h g-1 at 50 C, and a capacity retention of 94.7% and an average Coulombic efficiency of 99.8% for 500 charge/discharge cycles. Concentration polarization was deliberately introduced to fabricate a three-dimensional ordered Zn metal anode, which enabled a high-performance aqueous Ni-Zn battery at an extremely high rate of 50 C.
引用
收藏
页码：7467 / 7470
页数：4
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