Palladium-Catalyzed Decarboxylative Annulation Reaction of Aryl Iodides and Methyl 2-Haloarenecarboxylates

被引：0
|
作者：
Fu, Ying [1 ]
Chen, Xi [1 ]
Chen, Hao [1 ]
Liu, Jia-Jia [1 ]
Du, Zhengyin [1 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Ecofunct Polymer Mat, Minist Educ, Lanzhou 730070, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 25期
基金：
中国国家自然科学基金;
关键词：
REGIOSELECTIVE SYNTHESIS; COUPLING REACTIONS; FUNCTIONALIZATION; ARYLATION; EXTENSION; HALIDES;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A ligand-free palladium-catalyzed and norbornadiene-mediated annulation reaction of iodoarenes with methyl 2-haloarenecarboxylates is reported. The sequentially accomplished reaction comprises intermolecular C-H arylation, followed by intramolecular decarboxylative annulation, affording various valuable phenanthrenes. This reaction protocol could be expanded to triphenylene syntheses whereby norbornene was the cocatalyst. Interestingly, the decarboxylation of methyl esters was accomplished via solvent-mediated C-Me-O bond cleavages.
引用
收藏
页码：5253 / 5257
页数：5
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