Luminescence enhancement of LiSrPO4:Eu2+ phosphor by Mg2+ ion addition

被引:5
|
作者
Kamei S. [1 ]
Hatsumori T. [2 ]
Hasegawa T. [3 ]
Ishigaki T. [4 ]
Uematsu K. [5 ]
Toda K. [2 ,5 ]
Sato M. [5 ]
机构
[1] Department of Sustainable Engineering, College of Industrial Technology, Nihon University, Narashino
[2] Graduate School of Science and Technology, Niigata University, Niigata
[3] Faculty of Agriculture and Marine Science, Kochi University, Nankoku city
[4] Tottori University Cross-Informatics Research Center, Tottori
[5] Department of Chemistry and Chemical Engineering, Niigata University, Niigata
来源
Mater. Res. Innov. | 2019年 / 6卷 / 359-362期
基金
日本学术振兴会;
关键词
chemical synthesis; inorganic compounds; Optical materials; phosphors;
D O I
10.1080/14328917.2018.1482650
中图分类号
学科分类号
摘要
Mg-doped LiSrPO4:Eu2+ (Li(Sr, Mg)PO4:Eu2+) phosphors, in which some Sr2+ ions were replaced by Mg2+ ions, were prepared using a conventional solid-state reaction method. The crystal structure of the phosphors was hexagonal, which is the high-temperature phase of LiSrPO4, even though synthesis was carried out at a relatively low temperature of 900 °C. Fluorescence could be efficiently excited in the 220–400 nm ultraviolet region, and bright blue emission was produced with a peak at 448 nm. The emission intensity was higher than that for LiSrPO4:Eu2+ without Mg doping, and a lower Eu content (1 mol%) was required in order to reach the maximum intensity. These results indicate that the blue-emitting Li(Sr, Mg)PO4:Eu2+ phosphor is a promising candidate for phosphor-conversion white Light Emitting Diodes. © 2018, © 2018 Informa UK Limited, trading as Taylor & Francis Group.
引用
收藏
页码:359 / 362
页数:3
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