Chemoselective Electro-oxidation of Allyl Arene to Ester

被引：0
|
作者：
Li Mengfan [1 ]
Cheng Xu [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Nanjing 210023, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 44卷 / 03期
基金：
中国国家自然科学基金;
关键词：
allyl; benzyl; electrochemistry; esterification; ACTIVATION; OXIDATION; ALCOHOLS;
D O I：
10.6023/cjoc202309019
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An electrochemical C-H and C-C bond esterification reaction with allyl arene as a substrate is reported. This oxidation takes place selectively at the benzyl(+) allyl C-H site instead of other benzylic C-H groups. Since the reaction does not require acid/base catalysis for esterification, tertiary alcohol is suitable for the synthesis of the corresponding ester. In addition, side reactions such as transesterification can be avoided with this neutral protocol.
引用
收藏
页码：1005 / 1012
页数：8
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