Upconversion Luminescence and Optical Temperature Sensing Properties for Lu2O3(Y2O3):Yb3+/Er3+/Gd3+ Phosphors

被引:0
|
作者
Zhang Y.-H. [1 ]
Liu D. [1 ]
Wang T.-T. [1 ]
Jia H. [1 ]
Liu H. [1 ]
Fu Z.-L. [2 ]
机构
[1] Department of Electronic and Computer, Jilin Jianzhu University, Changchun
[2] School of Physics, Jilin University, Changchun
来源
基金
中国国家自然科学基金;
关键词
Fluorescence intensity ratio; Sensitivity; Sol-gel method;
D O I
10.3788/fgxb20194012.1478
中图分类号
学科分类号
摘要
Lu2O3(Y2O3):Yb3+/Er3+/Gd3+ phosphors were synthesized using a sol-gel method.Upconversion(UC) luminescence and temperature-sensing properties were investigated. Under 980 nm excitation, bright green, red, and weak ultraviolet emissions were observed. The optimal Gd3+ doping concentrations in Lu2O3(Y2O3) was 10%. The energy transfer processes from Er3+ to Gd3+ ions has been investigated and discussed. By utilizing the fluorescence intensity ratio (FIR) technique, the temperature sensing behaviors of the optimal sample are investigated based on the thermally coupled levels of 2H11/2 and 4S3/ 2 of Er3+ ions from 313 K to 573 K. The maximal sensitivity was gained to be 0.005 91 K-1 for Y2O3:1%Er3+/1%Yb3+/10%Gd3+. © 2019, Science Press. All right reserved.
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页码:1478 / 1485
页数:7
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共 24 条
  • [1] Prasad P.N., Nanophotonics, (2004)
  • [2] Wang Y.H., Shen P., Li C.Y., Et al., Upconversion fluorescence resonance energy transfer based biosensor for ultrasensitive detection of matrix metalloproteinase-2 in blood, Anal. Chem., 84, 3, pp. 1466-1473, (2012)
  • [3] Li Z.Q., Li X.D., Liu Q.Q., Et al., Core/shell structured NaYF<sub>4</sub>: Yb<sup>3+</sup>/Er<sup>3+</sup>/Gd<sup>+3</sup> nanorods with Au nanoparticles or shells for flexible amorphous silicon solar cells, Nanotechnology, 23, 2, (2012)
  • [4] Liu J.A., Bu W.B., Zhang S.J., Et al., Controlled synthesis of uniform and monodisperse upconversion core/mesoporous silica shell nanocomposites for bimodal imaging, Chem.-A Eur. J., 18, 8, pp. 2335-2341, (2012)
  • [5] Dai Y.L., Ma P.A., Cheng Z.Y., Et al., Up-conversion cell imaging and pH-induced thermally controlled drug release from NaYF<sub>4</sub>: Yb<sup>3+</sup>/Er<sup>3+</sup>@hydrogel core-shell hybrid microspheres, ACS Nano, 6, 4, pp. 3327-3338, (2012)
  • [6] Wang C., Cheng L., Liu Z., Upconversion nanoparticles for photodynamic therapy and other cancer therapeutics, Theranostics, 3, 5, pp. 317-330, (2013)
  • [7] Chen G.Y., Ohulchanskyy T.Y., Kumar R., Et al., Ultrasmall monodisperse NaYF<sub>4</sub>: Yb<sup>3+</sup>/Tm<sup>3+</sup> nanocrystals with enhanced near-infrared to near-infrared upconversion photoluminescence, ACS Nano, 4, 6, pp. 3163-3168, (2010)
  • [8] Chen G.Y., Liu H.C., Liang H.J., Et al., Upconversion emission enhancement in Yb<sup>3+</sup>/Er<sup>3+</sup>-codoped Y<sub>2</sub>O<sub>3</sub> nanocrystals by tridoping with Li<sup>+</sup> ions, J. Phys. Chem. C, 112, 31, pp. 12030-12036, (2008)
  • [9] Schietinger S., Aichele T., Wang H.Q., Et al., Plasmon-enhanced upconversion in single NaYF<sub>4</sub>: Yb<sup>3+</sup>/Er<sup>3+</sup> codoped nanocrystals, Nano Lett., 10, 1, pp. 134-138, (2010)
  • [10] Han P.D., Jiang X.P., Cheng S., Et al., Upconversion luminescent materials of Y-Gd oxysulfide binary system codoped with Yb and Er, J. Mater. Sci.: Mater. Electron., 26, 9, pp. 6599-6605, (2015)