Side-On Bonded Beryllium Dinitrogen Complexes

被引：0

作者：

Deng, Guohai ^{[1
]}

Pan, Sudip ^{[2
,3
]}

Wang, Guanjun ^{[1
]}

Zhao, Lili ^{[2
]}

Zhou, Mingfei ^{[1
]}

Frenking, Gernot ^{[2
,3
]}

机构：

[1] Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai,200438, China

[2] Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing,211816, China

[3] Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, Marburg,35043, Germany

来源：

Advanced Materials | 2020年 / 132卷 / 26期

关键词：

Nitrogen;

D O I：

10.1002/ANGE.202002621

中图分类号：

学科分类号：

摘要：

The preparation and spectroscopic identification of the complexes NNBe(η2-N2) and (NN)2Be(η2-N2) and the energetically higher lying isomers Be(NN)2 and Be(NN)3 are reported. NNBe(η2-N2) and (NN)2Be(η2-N2) are the first examples of covalently side-on bonded N2 adducts of a main-group element. The analysis of the electronic structure using modern methods of quantum chemistry suggests that NNBe-(η2-N2) and (NN)2Be(η2-N2) should be classified as π complexes rather than metalladiazirines. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10690 / 10696

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