Kinetics of Indium Leaching from High Indium Sphalerite in Oxygen Pressure Acid Leaching Process

被引:0
|
作者
Fan Y.-Y. [1 ]
Liu Y. [1 ]
Niu L.-P. [1 ]
Zhang T.-A. [1 ]
机构
[1] Key Laboratory of Ecological Metallurgy of Multi-metal Intergrown Ores of Ministry of Education, Northeastern University, Shenyang
关键词
High indium sphalerite; Indium; Kinetics; Leaching; Oxygen pressure acid leaching;
D O I
10.12068/j.issn.1005-3026.2019.09.008
中图分类号
学科分类号
摘要
Indium is an important multi-purpose strategic metal and has many potential high-valuable industrial applications. However, there are no independent deposits, often associated with sulfide ore such as lead and zinc. In this work, the indium leaching kinetics of oxygen pressure acid leaching were studied under a traditional electric heating condition. The effects of particle size, temperature, H2SO4 concentration, and oxygen partial pressure on leaching rate of indium were investigated. Indium leaching kinetics was studied using a "liquid-solid phase leaching reaction kinetics model with solid product layer". The results showed that indium leaching process was controlled by interfacial chemical reaction with the apparent activation energy of 69.735 kJ/mol. Moreover, the leaching efficiency of indium increased with the increase of the initial acid concentration, oxygen partial pressure, leaching temperature, and the decrease of particle size. © 2019, Editorial Department of Journal of Northeastern University. All right reserved.
引用
收藏
页码:1257 / 1262
页数:5
相关论文
共 13 条
  • [1] Schmuhl R., Smit J.T., Marsh J.H., The influence of microwave pre-treatment of the leach behaviour of disseminated sulphide ore, Hydrometallurgy, 108, 3, pp. 157-164, (2011)
  • [2] Virolainen S., Ibana D., Paatero E., Recovery of indium from indium tin oxide by solvent extraction, Hydrometallurgy, 107, 1, pp. 56-61, (2011)
  • [3] Alfantazi A.M., Moskalyk R.R., Processing of indium: a review, Minerals Engineering, 16, 8, pp. 687-694, (2003)
  • [4] Al-Harahsheh M., Kingman S.W., Microwave-assisted leaching-a review, Hydrometallurgy, 73, 3, pp. 189-203, (2004)
  • [5] Bayca S.U., Microwave radiation leaching of colemanite in sulfuric acid solutions, Separation & Purification Technology, 105, 105, pp. 24-32, (2013)
  • [6] Haque K.E., Microwave energy for mineral treatment processes-a brief review, International Journal of Mineral Processing, 57, 1, pp. 1-24, (1999)
  • [7] Xie K.Q., Yang X.W., Wang J.K., Et al., Kinetic study on pressure leaching of high iron sphalerite concentrate, Transactions of Nonferrous Metals Society of China, 17, 1, pp. 187-194, (2007)
  • [8] Christopher G., Weisener R.S.C.S., Gerson A.R., A comparison of the kinetics and mechanism of acid leaching of sphalerite containing low and high concentrations of iron, Mineral Processing, 74, 4, (2004)
  • [9] Safari V., Arzpeyma G., Rashchi F., Et al., A shrinking particle-shrinking core model for leaching of a zinc ore containing silica, Mineral Processing, 93, 1, (2009)
  • [10] Xie K.-Q., Yang X.-W., Shu Y.-Z., Et al., Study of acid leaching under pressure on polymetallic sulphide flotation concentrate, Nonferrous Metal(Extractive Metallurgy), 4, 6, pp. 6-9, (2006)