Photochemical water splitting via transition metal complexes

被引：1
|
作者：
Martinez, Antonio Rosales [1 ]
Rodriguez-Garcia, Ignacio [2 ]
机构：
[1] Univ Seville, Escuela Politecn Super, Dept Chem Engn, Seville 41011, Spain
[2] Univ Almeria, Dept Chem & Phys, Almeria 04120, Spain
来源：
JOURNAL OF CATALYSIS | 2024年 / 432卷
基金：
欧盟地平线“2020”;
关键词：
Water splitting; Titanocene; Transition metal complexes; Photochemical; Hydrogen; TI-III; HYDROGEN; ACTIVATION; MECHANISM; ENERGIES; OSMOCENE; OXYGEN; LIGHT;
D O I：
10.1016/j.jcat.2024.115415
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Photochemical water splitting by transition metal complexes provides a new approach to the production of hydrogen as a clean and sustainable energy carrier. Several selected systems are analyzed, and the two basic half reactions in the water splitting process which generates hydrogen and the compound of water oxidation (oxygen or hydrogen peroxide) are presented. Finally, a system designed for photochemical water splitting, based on the radical and organometallic chemistry of titanocene(III), is postulated.
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页数：6
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