Starch-supported cuprous iodide nanoparticles catalysed C-C bond cleavage: use of carbon-based leaving groups for bisindolylmethane synthesis

被引：0

作者：

Suresh, Muthiah ^{[1
]}

Singh, Raj Bahadur ^{[1
]}

Katlakunta, Sadhana ^{[2
]}

Patra, Snigdha Rani ^{[1
]}

Tanwer, Yogesh Bhaskar Singh ^{[1
]}

Mallick, Sadhucharan ^{[3
]}

Bhunia, Sabyasachi ^{[1
]}

Das, Debjit ^{[4
]}

机构：

[1] Cent Univ Jharkhand, Dept Chem, Ranchi, Jharkhand, India

[2] Saifabad Osmania Univ, Univ Coll Sci, Dept Phys, Hyderabad, Telangana, India

[3] Indira Gandhi Natl Tribal Univ, Cent Univ, Dept Chem, Amarkantak, India

[4] Triveni Devi Bhalotia Coll, Raniganj, India

来源：

MONATSHEFTE FUR CHEMIE | 2024年 / 155卷 / 07期

关键词：

Nanocatalysis; CuI NPs; C-C bond cleavage; Bisindolylmethane; 1,3-Dicyanide; SUBSTITUTION-REACTIONS; FACILE SYNTHESIS; BIS(INDOLYL)METHANES; ACTIVATION; FUNCTIONALIZATION; EFFICIENT; ALDEHYDES; INDOLES;

D O I：

10.1007/s00706-024-03215-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A starch-supported cuprous iodide nanoparticles (CuI-NPs@starch) catalysed C-C bond cleaving reaction involving carbon-based leaving groups like malononitrile, ethyl cyanoacetate, acetylacetone, and Meldrum's acid has been developed under moisture and air insensitive conditions. This competent C-C bond cleavage reaction is studied in detail as an attractive alternative method to synthesize biologically relevant bisindolylmethanes in moderate to good yields. The CuI-NPs@starch are synthesized in aqueous medium and characterized by X-ray powder diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy studies.

引用

页码：739 / 745

页数：7

共 2 条

[1] Carbon-based nucleophiles as leaving groups in organic synthesis via cleavage of C-C sigma bonds
Bhunia, Sabyasachi
Das, Debjit
[J]. TETRAHEDRON, 2022, 112
[2] Eco-friendly design of TiO2 nanoparticles supported on Fe3O4 coated carbon-based biochar substrate for the synthesis of pyrano-[2, 3-c]-pyrazole derivatives
Dharmendra, Dharmendra
Chundawat, Priyanka
Vyas, Yogeshwari
Chaubisa, Purnima
Kumawat, Monika
Ameta, Chetna
[J]. SUSTAINABLE CHEMISTRY AND PHARMACY, 2022, 28

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