Effects of Synthesis and Film Preparation Conditions on Properties of CsPbBr3 Inorganic Perovskite Quantum Dots

被引:0
|
作者
Ma X. [1 ]
Zhuang S.-W. [1 ]
Han L.-J. [1 ]
Hu D.-Q. [1 ]
Zhang Y.-T. [1 ]
Dong X. [1 ]
Wu G.-G. [1 ]
Zhang B.-L. [1 ]
机构
[1] State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University, Changchun
来源
基金
中国国家自然科学基金;
关键词
CsPbBr[!sub]3[!/sub; Perovskite; Photoluminesecence(PL); Quantum dot; TEM;
D O I
10.3788/fgxb20194008.0949
中图分类号
学科分类号
摘要
By a series of characterization of quantum dots and their films for different synthesis conditions and preparation parameters, the synthesis conditions of cesium lead bromide quantum dots and the quantum dots film preparation parameters are optimized. The effects of reaction temperature and reaction time on the properties of CsPbBr3 perovskite quantum dots were studied by thermal injection. The quantum dot samples of perovskite under different synthetic conditions were obtained and characterized. Then all CsPbBr3 quantum dot samples were prepared into thin films to explore its photoluminescence properties. When the reaction temperature is 180℃, the reaction time is 5 s, the quantum dot size is 9 nm, reaching the minimum value. With the spin speed of 3 000 r/min, the annealing temperature of 80℃ and the annealing time of 10 min, the CsPbBr3 quantum dots film has the strongest photoluminescence intensity. The optimum synthesis conditions of CsPbBr3 quantum dots and the CsPbBr3 quantum dots film preparation conditions were obtained. © 2019, Science Press. All right reserved.
引用
收藏
页码:949 / 955
页数:6
相关论文
共 18 条
  • [1] Liu M.Z., Johnston M.B., Snaith H.J., Efficient planar heterojunction perovskite solar cells by vapour deposition, Nature, 501, 7467, pp. 395-398, (2013)
  • [2] Tan Z.K., Moghaddam R.S., Lai M.L., Et al., Bright light-emitting diodes based on organometal halide perovskite, Nat. Nanotechnol., 9, 9, pp. 687-692, (2014)
  • [3] Zhang Q., Ha S.T., Liu X.F., Et al., Room-temperature near-infrared high-Q perovskite whispering-gallery planar nanolasers, Nano Lett., 14, 10, pp. 5995-6001, (2014)
  • [4] Dou L.T., Yang Y.M., You J.B., Et al., Solution-processed hybrid perovskite photodetectors with high detectivity, Nat. Commun., 5, (2014)
  • [5] Noh J.H., Im S.H., Heo J.H., Et al., Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells, Nano Lett., 13, 4, pp. 1764-1769, (2013)
  • [6] Liu Z.Z., Yang J., Du J., Et al., Robust subwavelength single-mode perovskite nanocuboid laser, ACS Nano., 12, 6, pp. 5923-5931, (2018)
  • [7] Wang W., Li Y., Ning P.F., Et al., Perovskite quantum dot/powder phosphor converted white light LEDs with wide color gamut, Chin. J. Lumin., 39, 5, pp. 627-632, (2018)
  • [8] Yu B.H., Lu H.G., Rao L.S., Et al., Synthesis of high quality inorganic perovskite quantum dots via microchannel reactor and their application in LED, Chin. J. Lumin., 39, 4, pp. 440-448, (2018)
  • [9] Protesescu L., Yakunin S., Bodnarchuk M.I., Et al., Nanocrystals of cesium lead halide perovskites (CsPbX<sub>3</sub>, X=Cl, Br, and I): novel optoelectronic materials showing bright emission with wide color gamut, Nano Lett., 15, 6, pp. 3692-3696, (2015)
  • [10] Abdi-Jalebi M., Andaji-Garmaroudi Z., Cacovich S., Et al., Maximizing and stabilizing luminescence from halide perovskites with potassium passivation, Nature, 555, 7697, pp. 497-501, (2018)