Advance of Single-Atom Catalysts Confined into Pristine Metal-Organic Frameworks and their Energy-Related Applications

被引：0

作者：

Mo, Qijie ^{[1
]}

Chen, Chunying ^{[1
]}

Li, Sihong ^{[1
]}

Liu, Jiewei ^{[2
]}

Zhang, Li ^{[1
]}

Su, Cheng-Yong ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Lehn Inst Funct Mat, Sch Chem, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510006, Peoples R China

[2] Wuyi Univ, Inst Carbon Peaking & Carbon Neutralizat, Sch Environm & Chem Engn, Jiangmen Key Lab Synthet Chem & Cleaner Prod, Jiangmen 529020, Peoples R China

来源：

CHEMCATCHEM | 2024年 / 16卷 / 16期

基金：

中国国家自然科学基金;

关键词：

single-atom catalysts; metal-organic frameworks; synthetic strategy; small molecule activation; CO2; CONVERSION; HYDROGEN; REDUCTION; PORPHYRIN; SITES; MOF; INTERSPACES; STRATEGIES; OXIDATION; CENTERS;

D O I：

10.1002/cctc.202301753

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal single-atom catalysts (SACs) play an essential role in small molecule related energy conversion. Metal-organic frameworks (MOFs), which contain the highly ordered arrays of organic linkers and metal nodes, as well as the clearly defined pore structures, are considered as an ideal platform to fabricate atomically dispersed metal sites. In this review, we summarize the approaches for fabricating MOF-based SACs by utilizing their structure characteristics. A brief discussion is also given about the feasible techniques to characterize SACs. A series of representative examples of MOF-based SACs and their energy-related applications, mainly in photocatalysis and electrocatalysis, are discussed. The challenges and future development opportunities of MOF-based SACs are highlighted. MOF supported single-atom catalysts (SACs) have been shown remarkable potential in the energy-related application. This review summaries the reported fabrication strategies, characterizations, and energy related applications of MOF-based SACs, and highlight the challenges and future directions of MOF-based SACs. image

引用

页数：13

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