Effect of structured 5A molecular sieve adsorption bed structure and process parameters on N2/H2 adsorption performance

被引:0
|
作者
Wang P. [1 ]
Liu J. [1 ]
Zhang S. [2 ]
Fan D. [2 ]
Zhang Y. [2 ]
Xu H. [1 ]
机构
[1] State Key Laboratory of Chemical Engineering, School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai
[2] China Petrochemical(Dalian) Petrochemical Research Institute, Dalian, 116050, Liaoning
来源
Huagong Xuebao/CIESC Journal | 2020年 / 71卷 / 07期
关键词
Adsorption performance; Hydrogen purification; Kinetic modeling; Structured 5A molecular sieve;
D O I
10.11949/0438-1157.20191349
中图分类号
学科分类号
摘要
The kinetic parameters were obtained by adsorption isotherm, and the CFD model was established to simulate the adsorption process of hydrogen/nitrogen in the structured 5A molecular sieve adsorption bed. The effects of structural parameters such as the adsorbent sheet spacing and thickness and process parameters such as adsorption pressure and volume flow rate on the adsorption performance to the mixed gas were discussed. The results show that reducing sheet spacing and thickness are beneficial to the mass transfer coefficient and bed saturation degree. Increasing the adsorption pressure can improve the bed saturation degree, but will reduce the mass transfer coefficient. The effect of the flow rate on mass transfer coefficient is not obvious, but when the flow rate is high, both the adsorption capacity and the bed saturation degree decrease. The structured 5A molecular sieve adsorbent has good adsoption performance. © All Right Reserved.
引用
收藏
页码:3114 / 3122
页数:8
相关论文
共 30 条
  • [1] Zhang S Y, Xie P F, Tian Z X, Et al., Application of membrane separation technology in hydrogen recovery from catalytic reforming PSA tail gas, Contemporary Chemical Industry, 48, 3, pp. 643-646, (2019)
  • [2] Fang L, Xiao J S, Benard P, Et al., Thermal effects on pressure swing adsorption cycles for hydrogen purification, Journal of Engineering Thermophysics, 39, 5, pp. 168-175, (2018)
  • [3] Tian J J, Wang X Y, Yang X M, Et al., Study on recovery of hydrogen from hydrogen containing gas in the refinery, Petroleum Refinery Engineering, 46, 5, pp. 6-9, (2016)
  • [4] Cao W B, Wang L J, Li X., Fabrication of wall-flow honeycomb micro packed bed and application in pressure swing adsorption process, Journal of Zhejiang University (Engineering Science), 51, 4, pp. 777-783, (2017)
  • [5] Ichiura H, Kubata Y, Wu Z H, Et al., Preparation of zeolite sheet using a papermaking technique, Journal of Materials Science, 36, 4, pp. 913-917, (2001)
  • [6] Jose A D, Agueda V I, Uguina M A, Et al., Adsorption and diffusion of H<sub>2</sub>, CO, CH<sub>4</sub>, and CO<sub>2</sub> in BPL activated carbon and 13X zeolite: evaluation of performance in pressure swing adsorption hydrogen purification by simulation, Industrial & Engineering Chemistry Research, 53, 40, pp. 15414-15426, (2014)
  • [7] Guo H L., Research on solid adsorbent, China Petroleum and Chemical Standard and Quality, 34, 6, (2014)
  • [8] Duan X, Lu J., Two-Dimensional Nanocomposite Hydroxides: Structure, Assembly and Function, pp. 28-35, (2013)
  • [9] Moran A, Talu O., The role of pressure drop on rapid pressure swing adsorption performance, Industrial & Engineering Chemistry Research, 56, 19, pp. 5715-5723, (2017)
  • [10] Bowie G K, Denis J C., Pressure swing adsorption with axial or centrifugal compression machinery