The Activity of Trimetallic Catalysts in the Hydrotreating of a Mixed Diesel Fraction

被引：0
|
作者：
Arkhipova, I. A. [1 ]
Petrova, E. G. [1 ]
Fadeev, V. V. [1 ]
Zaglyadova, S. V. [1 ]
Kuptsov, A. Kh. [1 ]
Chernysheva, E. A. [2 ]
机构：
[1] United Res & Dev Ctr LLC, Brentwood, NH 03833 USA
[2] Gubkin Univ, Moscow, Russia
来源：
CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS | 2024年 / 60卷 / 03期
关键词：
trimetallic hydrotreating catalysts; acid sites; impregnation solution; Raman spectrum; desulfurization;
D O I：
10.1007/s10553-024-01707-9
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
A study was carried out on the effect of the nature of the support, composition of the active phase, and heat treatment conditions on the activity of trimetallic Ni-Co-Mo catalysts in the hydrotreating of a mixed diesel fraction. Temperature-programmed desorption was used to show the effect of the amount and strength of the acid sites of the support on the activity of catalysts with the same elemental composition. We established the nickel-to-cobalt as well as phosphorus-to-molybdenum ratios in these trimetallic hydrotreating catalysts corresponding to the greatest desulfurization and minimum formation of polycyclic aromatic hydrocarbons in the hydrogenate.
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收藏
页码：522 / 529
页数：8
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