New multiple-layered 3D polymers showing aggregation-induced emission and polarization

被引:4
|
作者
Zhang, Sai [1 ]
Yuan, Qingkai [2 ]
Li, Guigen [2 ]
机构
[1] Changzhou Univ, Sch Pharm, Continuous Flow Engn Lab Natl Petr & Chem Ind, Changzhou 213164, Jiangsu, Peoples R China
[2] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA
基金
中国国家自然科学基金;
关键词
CONJUGATION;
D O I
10.1039/d4ra02128b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An exceptional achiral and chiral multilayer 3D polymer has been created and controlled by uniform and distinct aromatic chromophore units that are multiply sandwiched by naphthyl berths. In order to put together this assembly, it was necessary to search for new catalytic Suzuki-Miyaura polycouplings among various catalytic systems, monomers, and catalysts. Gel Permeation Chromatography (GPC) was able to verify the presence of many framework layers. The resulting achiral and chiral polymers displayed notable optical characteristic. An exceptional achiral and chiral multilayer 3D polymer has been created and controlled by uniform and distinct aromatic chromophore units that are multiply sandwiched by naphthyl berths.
引用
收藏
页码:13342 / 13350
页数:9
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