Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

被引：0
|
作者：
Nurhasni, Nurhasni [1 ]
Adawiah, Adawiah [2 ]
Wahyudin, Wahyudin [3 ]
Hadriyani, Rizka [1 ]
Andriyani, Leni [1 ]
Fadhilla, Rizkha [1 ]
Zulys, Agustino [4 ]
Sukandar, Dede [1 ]
机构：
[1] UIN Syarif Hidayatullah Jakart, Fac Sci & Technol, Dept Chem, Jl Ir H Juanda 95, Tangerang 15412, Selatan, Indonesia
[2] UIN Syarif Hidayatullah, Fac Sci & Technol, Integrated Lab Ctr, Jakarta, Indonesia
[3] Natl Res & Innovat Agcy, Res Ctr Adv Mat, KST BJ Habibie, Jl Ir H Juanda 95, South Tangerang 15314, Indonesia
[4] Univ Indonesia, Fac Math & Nat Sci, Dept Chem, Jl Lingkar Kampus Raya, Depok 16424, Jawa Barat, Indonesia
来源：
BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS | 2024年 / 19卷 / 01期
关键词：
Keywords : Adsorbent; Cd 2+; Pb 2+; Cr-PTC-HIna; sonochemical; EFFICIENT REMOVAL; ELIMINATION; CD(II); PB(II); PB2+;
D O I：
10.9767/bcrec.20069
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
As an adsorbent material, Metal-Organic Framework (MOF) provides several advantages, such as large surface area and pore volume, as well as stability in aqueous systems both in acidic, basic, and neutral conditions. The research successfully made a metal organic framework (MOF) from chromium and perylene that was modulated by isonicotinic acid. It was done using three different methods: hydrothermal (Cr-PTC-HIna-HT), solvothermal (Cr-PTC-HIna-ST), and sonochemical (Cr-PTC-HIna-SC). The Cr-PTC-HIna-SC showed the greatest Pb2+ ion adsorption capacity. The optimum adsorption of Pb2+ ions occurred at 150 ppm Pb2+ ion concentration, pH of 5, 90 min of contact time, and an adsorption capacity of 149.95 mg/g at 35 degrees C. The dominant adsorption isotherm model is the Langmuir isotherm model with R-2 = 0.9867 and follows the pseudo-second-order. The selectivity test showed that Cr-PTC-HIna-SC MOF could adsorb more Cd2+ ions than Pb2+ ions, with 250 mg/g being the best amount.
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页码：86 / 98
页数：13
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