Determination of Residues of Five Carbamate Pesticides in Spinach by QuEChERS Coupled with UPLC-MS/MS

被引：0
|
作者：
Feng W. [1 ]
Luo H. [1 ]
Huang Z. [1 ]
机构：
[1] Guangzhou Inspection and Testing Certification Group Co, Guangzhou
来源：
Journal of Food Science and Technology (China) | 2019年 / 37卷 / 03期
关键词：
Carbamate; Pesticide residue; QuEChERS; Spinach; UPLC-MS/MS;
D O I：
10.3969/j.issn.2095-6002.2019.03.013
中图分类号：
学科分类号：
摘要：
An ultra performance liquid chromatography-tandem mass spectrometry (UPLC- MS /MS) method for the determination of five carbamate pesticides in spinach was established. Samples were homogenized and extracted by ultrasonic with acetonitrile-water(50:50 in volume ratio), and then salted out and purified with primary secondary amine sorbent. Under the electrospray ionization (ESI+mode), data of the target parent ions and product ions were collected with mass spectrometric multi-response monitoring scanning detection. The matrix calibration curves of five carbamate pesticides showed the good linearity within the concentrations of 0.1-20.0 μg/L with the good correlation coefficient (r>0.999 1). The average recoveries of three spiked levels ranged from 91.0%-101.0%, while the limits of detection and limits of quantitation were 0.10-0.20 μg/kg and 0.25-0.50 μg/kg, respectively. The relative standard deviations were 2.15%-5.57%. This method has good sensitivity and high precision, which is suitable for practical determination of five carbamate pesticides in spinach. © 2019, Editorial Department of Journal of Food Science and Technology. All right reserved.
引用
收藏
页码：100 / 104
页数：4
相关论文
共 15 条
  • [1] Wu Z.P., Gao W., Yang H., Et al., Progress on the analysis of carbamate pesticide residues, Jiangsu Chemical Industry, 32, 5, pp. 24-27, (2004)
  • [2] Li Z.W., Liang D., Zhang J.F., Progress on analytical methods for carbamate pesticide residues, Journal of Huazhong Agricultural University, 27, 5, pp. 691-695, (2008)
  • [3] Gupta R.C., Toxicology of organophosphate and carbamate compounds, (2006)
  • [4] Karami-Mohajeri S., Abdollahi M., Toxic influence of organophosphate, carbamate, and organochlorine pesticides on cellular metabolism of lipids, proteins, and carbohydrates: a systematic review, Human & Experi-Mental Toxicology, 30, 9, pp. 1119-1140, (2011)
  • [5] Song Z.P., Tian S.L., Wang D.H., Et al., An analytical study on organophosphorus and carbamate pesticide residues in vegetables by GC-TSD, Journal of Gansu Sciences, 18, 2, pp. 28-30, (2006)
  • [6] Shao J.L., Li Q.W., Liu H.C., Et al., Determination of eight carbamate pesticides in vegetables by high perfor-mance liquid chromatography, Modern Food Science and Technology, 27, 7, pp. 856-860, (2011)
  • [7] Mao X.H., Jia Z.W., Miao S., Et al., HPLC for the simultaneous determination of 13 pesticides in traditional Chinese herbal medicines, Chinese Traditional Patent Medicine, 32, 3, pp. 454-459, (2010)
  • [8] Sun F.J., Li R.Y., Yuan X.R., Et al., Headspace solid-phase micro-extraction coupled with gas chromatography-mass spectrometric determination of carbamate pesticide residues in apples, Food Science, 31, 10, pp. 223-227, (2010)
  • [9] An K., Determination of residues of 7 kind of carbamate pesticides in vegetables by gas chromatography mass spectrometry, Chinese Journal of Health Laboratory Technology, 7, pp. 1531-1532, (2009)
  • [10] Titato G.M., Bicudo R.C., Lancas F.M., Optimization of the ESI and APCI experimental variables for the LC/MS determination of s-triazines, methylcarbamates, organophosphorous, benzimidazoles, carboxamide and phenylurea compounds in orange samples, Journal of Mass Spectrometry, 42, 10, pp. 1348-1357, (2010)
12