Physicochemical Characterization and Enzymatic Hydrolysis of Cellulosic Component Fractionated from Microwave Liquefied Lignocellulosic Biomass

被引:0
|
作者
Peng X. [1 ,2 ,3 ]
Nie S. [2 ]
Liu J. [3 ]
Cui Y. [2 ,4 ]
机构
[1] Key Laboratory of Tree Breeding and Cultivation of the National Forestry and Grassland Administration, Research Institute of Forestry, CAF, Beijing
[2] Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Guangxi University, Nanning
[3] National Engineering Laboratory for Tree Breeding, Beijing Forestry University, Beijing
[4] National Science Library, Chinese Academy of Sciences, Beijing
来源
Linye Kexue/Scientia Silvae Sinicae | 2019年 / 55卷 / 05期
关键词
Biofuel; Lignocellulose; Microwave liquefied; Physicochemical characterization;
D O I
10.11707/j.1001-7488.20190515
中图分类号
学科分类号
摘要
Objective: The development of a solvolysis process by combining microwave heating and glycerol is a promising method to enhance the economic viability of biorefinery. The application of this technology on the pretreatment of lignocellulosic biomass is of great significance. Method: The liquefaction treatment of Populus alba ×P. glandulosa 84 K, Larix kaempferi, Phyllostachys viridis and Panicum virgatum was carried out by microwave liquefaction method. The products were divided into liquid and solid cellulose components. Using cellulose as raw material, the cellulose components were comprehensively characterized. Result: The chemical analysis result showed that the cellulose fiber had high glucan content. Infrared spectroscopy showed that the signals of lignin and hemicelluloses gradually weakened, further confirming the effective removal of hemicelluloses and lignin in the liquefaction treatment. The result of XRD analysis showed that the cellulose fibers had high crystallinity and large surface area. Conclusion: Compared with the original lignocellulosic biomass, the enzymolysis saccharification efficiency of the cellulose fiber of four kinds of raw materials was not improved to a certain degree, indicating the potential of cellulose fiber in liquefied solid product in the preparation of fuel ethanol. © 2019, Editorial Department of Scientia Silvae Sinicae. All right reserved.
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页码:134 / 141
页数:7
相关论文
共 18 条
  • [1] Boudet A.M., Kajita S., Grima-Pettenati J., Et al., Lignins and lignocellulosics: a better control of synthesis for new and improved uses, Trends in Plant Science, 8, 12, pp. 576-581, (2003)
  • [2] French A.D., Idealized powder diffraction patterns for cellulose polymorphs, Cellulose, 21, 2, pp. 885-896, (2014)
  • [3] Himmel M.E., Ding S.Y., Johnson D.K., Et al., Biomass recalcitrance: engineering plants and enzymes for biofuels production, Science, 315, 5813, pp. 804-807, (2007)
  • [4] Huber G.W., Iborra S., Corma A., Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering, Chemical Reviews, 106, 9, pp. 4044-4098, (2006)
  • [5] Kucuk M.M., Delignification of biomass using alkaline glycerol, Energy Sources, 27, 13, pp. 1245-1255, (2005)
  • [6] Li Q., Song J., Peng S., Et al., Plant biotechnology for lignocellulosic biofuel production, Plant Biotechnology Journal, 12, 9, pp. 1174-1192, (2014)
  • [7] Li Z.Q., Jiang Z.H., Fei B.H., Et al., Comparison of bamboo green, timber and yellow in sulfite, sulfuric acid and sodium hydroxide pretreatments for enzymatic saccharification, Bioresource Technology, 151, pp. 91-99, (2014)
  • [8] Lissens G., Klinke H., Verstraete W., Et al., Wet oxidation pre-treatment of woody yard waste: parameter optimization and enzymatic digestibility for ethanol production, Journal of Chemical Technology & Biotechnology, 79, 8, pp. 889-895, (2004)
  • [9] Peng X.P., Wang B., Wen J.L., Et al., Effects of genetic manipulation (HCT and C3H down-regulation) on molecular characteristic of lignin and its bioconversion to fermentable sugars, Cellulose Chemistry and Technology, 50, 5-6, pp. 649-658, (2016)
  • [10] Perez J., Gonzalez A., Oliva J.M., Et al., Effect of process variables on liquid hot water pretreatment of wheat straw for bioconversion to fuel-ethanol in batch reactor, Journal of Chemical Technology & Biotechnology, 82, 10, pp. 929-938, (2007)