Research on mechanism and catalysts of CO2 electroreduction to formate

被引：0
|
作者：
Zhao P.-P. [1 ,2 ]
Lian H.-L. [1 ,2 ]
机构：
[1] Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou
[2] National Key Laboratory of Coking Coal Green Process Research, Zhengzhou
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2023年 / 51卷 / 11期
关键词：
catalyst; CO[!sub]2[!/sub] electroreduction; formate; reaction mechanism;
D O I：
10.19906/j.cnki.JFCT.2023048
中图分类号：
学科分类号：
摘要：
This paper reviews the latest progress in the field of CO2 electrocatalytic reduction to formate in the past five years. The reaction mechanism of CO2 electroreduction to formate and the types of catalysts used in this process are introduced, including metal catalysts, atomic dispersion catalysts, metal oxide catalysts, carbon materials, and composite material catalysts. The main factors affecting product selectivity, catalytic activity and stability are analyzed in detail from the perspectives of catalyst, electrolyte, reaction atmosphere and electrolytic cell. In view of the current research status of carbon dioxide electroreduction to formate, it is proposed to innovate on nanomaterials and composites, explore the active site and reaction path with the help of in-situ characterization technology, and guide the design and synthesis of efficient catalysts, improve the electrochemical reactor module to improve the catalytic efficiency and other issues can be regarded as the future research focus and development direction. © 2023 Science Press. All rights reserved.
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页码：1633 / 1651
页数：18
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