Removal of Lead Ions from Water by Struvite Natural Zeolite Composite

被引:0
|
作者
Deng M.-J. [1 ]
Wang X.-J. [1 ]
Cheng X.-J. [1 ]
Jing H.-P. [1 ]
Zhao J.-F. [1 ]
机构
[1] State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai
来源
Huanjing Kexue/Environmental Science | 2019年 / 40卷 / 03期
关键词
Absorb; Lead; Natural zeolite; Struvite;
D O I
10.13227/j.hjkx.201808098
中图分类号
学科分类号
摘要
A nitrogen and phosphorus recovery product (NZ-MAP) containing struvite was applied to remove heavy metal ions and lead from water. NZ-MAP was characterized using XRD, FTIR, and SEM/EDS. The effects of dosage, initial pH, and reaction time on the removal process were investigated. The results show that the main component of NZ-MAP is a natural zeolite loaded with struvite. When the dosage is 0.4 g•L-1, the maximum adsorption amount is 749.74 mg•g-1, and the adsorption of Pb2+ in the solution increases first and then tends to reach a balance with increase of the pH. Its removal mechanism is mainly Pb10(PO4)6(OH)2 precipitation, and the effect is best when pH is 5.0. The removal process of Pb2+ from water is more in line with the quasi-two stage kinetic model. In an investigation of the effect of coexisting heavy metal ions on the removal of lead ions in water by NZ-MAP, it was found that coexisting Ni2+ and Cu2+ have little effect on NZ-MAP adsorption on Pb2+. Coexisting Zn2+ and Al3+ obviously inhibit the adsorption of Pb2+ by NZ-MAP. The research shows that NZ-MAP material can remove lead ions from water efficiently, thus offering an effective method for doing this. © 2019, Science Press. All right reserved.
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页码:1310 / 1317
页数:7
相关论文
共 23 条
  • [1] Sun W.F., Xiao D., Status and control technology of heavy metal pollution, Energy and Energy Conservation, 2, pp. 49-50, (2012)
  • [2] Yu X.L., Liu Q., Research status of heavy metal pollution in waters and its effects on human health, Journal of Green Science and Technology, 10, pp. 123-126, (2011)
  • [3] Wang X.D., Tie S.L., Performance of nano-ZnO and its applications in coatings, Electroplating & Finishing, 24, 3, pp. 27-30, (2005)
  • [4] Zhu Y.M., Wang Z.A., Su X.J., Et al., Adsorption of Cu<sup>2+</sup> by Ca-bentonite in wastewater, Journal of Northeastern University (Natural Science), 27, 1, pp. 99-102, (2006)
  • [5] Meng X., Zhang X.D., Tian Y., Et al., Application of nanomaterials in coatings industry, Shandong Chemical Industry, 33, 3, pp. 19-21, (2004)
  • [6] Afkhami A., Saber-Tehrani M., Bagheri H., Simultaneous removal of heavy-metal ions in wastewater samples using nano-alumina modified with 2, 4-dinitrophenylhydrazine, Journal of Hazardous Materials, 181, 1-3, pp. 836-844, (2010)
  • [7] Zhong C.M., Fang X.H., Xu Z.L., Membrane technology and its application in heavy metal wastewater treatment, Environmental Science & Technology, 31, 8, pp. 44-48, (2008)
  • [8] Ma N., Liu H.B., Xie X.Y., Oxidation of cationic red 3R in water with H<sub>2</sub>O<sub>2</sub> catalyzed by mineral loaded with Fe/Co, Environmental Science, 36, 2, pp. 576-583, (2015)
  • [9] Park J.H., Bolan N., Megharaj M., Et al., Comparative value of phosphate sources on the immobilization of lead, and leaching of lead and phosphorus in lead contaminated soils, Science of the Total Environment, 409, 4, pp. 853-860, (2011)
  • [10] Huang H.M., Xu C.L., Zhang W., Removal of nutrients from piggery wastewater using struvite precipitation and pyrogenation technology, Bioresource Technology, 102, 3, pp. 2523-2528, (2011)