Effect of polyphenylene sulfide sulfone sizing agent on interfacial, thermal, and mechanical properties of carbon fiber

被引:0
|
作者
Zhuang, Yifan [1 ]
Liu, Haibin [1 ]
Zhou, Shaoyang [1 ]
Jia, Zhehao [1 ]
Sun, Ying [1 ]
机构
[1] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China
基金
上海市自然科学基金; 中国国家自然科学基金;
关键词
fibers; sizing agent; surfaces and interfaces; thermoplastics; SURFACE MODIFICATION; COMPOSITES; ADHESION; STRENGTH;
D O I
10.1002/app.55549
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyphenylene sulfide sulfone (PPSS) was synthesized by one-step method and utilized as a sizing agent for carbon fibers. The effects of various monomer ratios, reaction time, and reaction temperature were investigated on the molecular weight of PPSS. The thermal analysis revealed that the product PPSS exhibited a glass transition temperature exceeding 215.5 degrees C, indicating exceptional thermal stability. After PPSS sizing treatment, the grooves on the surface of carbon fibers were filled, resulting in a substantial enhancement of the microinterface properties. The surface energy was increased by 8.2%, while the maximum weight loss temperature was 27.8% higher than that of the commercial carbon fiber. The tensile strength of the carbon fiber after heat treatment reached 2196 MPa, representing a 45.9% increase over that of the commercial carbon fiber. The synthesis of PPSS as sizing agents and the improvement on the high-temperature resistance and mechanical properties of carbon fibers. image
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页数:10
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