Research progress on the synthesis and characterization of ammonia borane and metal nanocatalysts for hydrogen production the hydrolysis of ammonia borane

被引：2
|
作者：
Zou A.-H. [1 ,2 ]
Lin L.-H. [1 ]
Zhou L. [3 ]
Kang Z.-B. [1 ]
Cao L.-H. [4 ]
Han Q.-D. [5 ]
机构：
[1] School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang
[2] School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang
[3] HusT-wUxi Research Institute, Wuxi
[4] Facuity of Mechanical Materials, School of Science and Technology, Nanchang Hangkong University, Nanchang
[5] Taishan Science and Technology Research Institute, Taian
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2023年 / 51卷 / 07期
关键词：
ammonia borane; catalyst; hydrogen storage materials; hydrolysis of hydrogen; transition metal;
D O I：
10.1016/S1872-5813(23)60347-0
中图分类号：
学科分类号：
摘要：
Ammonia borane (AB) is a promising chemical hydrogen storage material with high hydrogen storage density (19.6%), which can release three molar equivalents of hydrogen through catalytic hydrolysis at room temperature. However, AB releases hydrogen slowly in water, it is necessary to develop highly active metal nanocatalysts to accelerate the process of hydrolysis. This article provides an overview of the synthesis and characterization methods of ammonia borane, the mechanism of hydrolysis and catalytic hydrogen production using the unique dihydrogen key in the ammonia borane structure, and the various factors that affect the hydrogen release performance of AB. © 2023 Science Press. All rights reserved.
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页码：909 / 920
页数：11
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