Effect of Molecular Structure of Curing Agent on Properties of Naringenin Epoxy

被引：0
|
作者：
Zhao G. [1 ]
Liu Z. [1 ]
Cheng Y. [1 ]
Li L. [1 ]
Ren S. [1 ,2 ]
Du Y. [1 ,2 ]
机构：
[1] School of Materials Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang
[2] Hebei Key Laboratory of Advanced Materials for Transportation Engineering and Environment, Shijiazhuang
来源：
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2023年 / 39卷 / 06期
关键词：
curing agent; epoxy resin; mechanical properties; naringenin;
D O I：
10.16865/j.cnki.1000-7555.2023.0132
中图分类号：
学科分类号：
摘要：
The naringenin bio- based epoxy matrix (NEP) was synthesized from the natural flavonoid naringenin. Four curing agents with different molecular structures, including maleic anhydride (MAH), 4,4-diaminodiphenylmethane (DDM), furfurylamine (FA) and 5,5-methylenedifurfurylamine (DFA) were used to cure NEP matrix respectively. By testing the mechanical properties, dynamic mechanical properties and thermal stability of the four cured products, the effect of the molecular structure of the curing agents on the properties of naringenin epoxy was explored. The results show that multifunctional amine curing agents with flexible structure are more favorable to the formation of high crosslinking structure. However, due to the steric hindrance effect, the crosslink density of multifunctional amine curing agents is still significantly lower than that of small molecule anhydride curing agents. Among them, NEP/MAH has the highest crosslink density and highest impact strength of 4.8 kJ/m2. The glass transition temperature and initial thermal degradation temperature are 188.3 ℃ and 314 ℃, respectively. © 2023 Chengdu University of Science and Technology. All rights reserved.
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页码：78 / 84
页数：6
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共 20 条
  • [1] Fadlallah S, Roy P S, Garnier G, Et al., Are lignin- derived monomers and polymers truly sustainable? An in- depth green metrics calculations approach, Green Chemistry, 23, pp. 1495-1535, (2021)
  • [2] Hou G X, Xie J Q, Li T T., Preparation and thermal properties of bio- based gallic epoxy resin/graphene oxide nanocomposites, Polymer Materials Science & Engineering, 32, 7, pp. 159-163, (2016)
  • [3] Flint S, Markle T, Thompson S, Et al., Bisphenol a exposure, effects, and policy: a wildlife perspective, Journal of Environmental Management, 104, pp. 19-34, (2012)
  • [4] Nikafshar S, Zabihi O, Hamidi S, Et al., A renewable bio- based epoxy resin with improved mechanical performance that can compete with DGEBA, RSC Advances, 7, pp. 8694-8701, (2017)
  • [5] Li M, Pu Y, Thomas V M, Et al., Recent advancements of plant-based natural fiber–reinforced composites and their applications, Composites Part B: Engineering, 200, (2020)
  • [6] Hernandez E D, Bassett A W, Sadler J M, Et al., Synthesis and characterization of bio-based epoxy resins derived from vanillyl alcohol, ACS Sustainable Chemistry & Engineering, 4, pp. 4328-4339, (2016)
  • [7] Radojcic D, Hong J, Petrovic Z S., From natural oils to epoxy resins: a new paradigm in renewable performance materials, Journal of Polymers and the Environment, 30, pp. 765-775, (2022)
  • [8] Xue B, Tang R, Xue D, Et al., Sustainable alternative for bisphenol a epoxy resin high- performance and recyclable lignin- based epoxy vitrimers, Industrial Crops and Products, 168, (2021)
  • [9] Li T, Liu X, Jiang Y, Et al., Bio-based shape memory epoxy resin synthesized from rosin acid, Iranian Polymer Journal, 25, pp. 957-965, (2016)
  • [10] Gao X, Wang G, Liu X H., Study on the adhesion properties of epoxy resin adhesive modified by polyepoxy cardanol glycidyl ether, Chemistry and Adhesion, 42, 6, pp. 437-440, (2020)
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