Selective electrochemical thiocyanation/selenocyanation of C(sp3)-H and C (sp2)-H bonds

被引：1
|
作者：
Wang, Zhihao [1 ]
Chen, Binbin [1 ]
Pang, Qing [1 ]
Xu, Jialei [1 ]
Shen, Jiabin [1 ]
Xu, Jun [1 ]
Li, Wanmei [1 ]
机构：
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Minist Educ,Key Lab Organosilicon Mat Technol, Hangzhou 311121, Peoples R China
来源：
MOLECULAR CATALYSIS | 2024年 / 559卷
关键词：
Thiocyanation/Selenocyanation; Nafimidone; Electrocatalysis; Oxidant-free; Selective synthesis ofC(sp3)-H andC(sp2)-H; THIOCYANATION; ACTIVATION;
D O I：
10.1016/j.mcat.2024.114060
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Herein, we report a general and eco-friendly electrochemical method for the selective thiocyanation/selenocyanation of C(sp3)-H and C(sp2)-H bonds in nitrogen -containing compounds under exogenous oxidant -free conditions. This is the first example of selective thiocyanation based on a nitrogen -containing compound with excellent regional principles and chemical selectivity for different reaction sites. This convenient and practical protocol has considerable potential for the modification of important structural backbones.
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页数：7
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