SynthesisandCrystalStructureofaNovelHeptanuclearRuthenium-andSodium-containingPolyoxomolybdate[{Na（H2O）3}2{Ru（dmso）3}2（MoO4）3]·3H2O

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作者：

HUANG XiHe XIANG ShengChang FU RuiBiao SHENG TianLu ZHANG JianJun LI YaMin WANG LongSheng WU XinTao State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China ^{[350002
]}

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来源：

结构化学 | 2006年 / 07期

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O631.3 [高聚物的化学性质];

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摘要：

The title compound, [{Na(H2O)3}2{Ru(dmso)3}2(MoO4)3]3H2O, has been ob- tained by the reaction of Na2MoO42H2O with cis-Ru(dmso)4Cl2 in aqueous solution. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the triclinic system, space group P1 with a = 12.3333(3), b = 12.6289(3), c = 32.0284(14) , α = 79.873(7), β = 87.549(9), γ = 64.500(4)o, V = 4429.5(2) 3, Z = 4, Mr = 1358.85, Dc = 2.038 g/cm3, F(000) = 2696 and μ = 1.874 mm-1. The compound contains a novel pentanuclear triangle bipyramidal core, [{Ru(dmso)3}2(MoO4)3]2-, which consists of two {Ru(dmso)3}2+ fragments and three {μ2-MoO4}2- units. Furthermore, the dmso ligands bridge the pentanuclear [Ru2Mo3] core and two [Na(H2O)3]+ fragments together, forming a neutral heptanuclear ruthenium- and sodium- containing polyoxomolybdate.

引用

页码：783 / 788

页数：6

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