SynthesisandCrystalStructureof{η5:η1-[（2-Methoxyphenyl）-isopropyl]-indenyl}（dimethoxyethylene）lithium1

被引：0
|
作者：
冯其琴
李一梅
王绍武
周双六
盛恩宏
黄子祥
机构：
[1] Institute of Organic Chemistry
[2] School of Chemistry and Materials Science
[3] Anhui Normal University
[4] Wuhu
[5] Anhui
[6] China
[7] China State Key Laboratory of Organometallic Chemistry
[8] Shanghai Institute of Organic Chemistry
[9] The Chinese Academy of Sciences
[10] Shanghai
[11] Fujian Institute of Research on the Structure of Matter
[12] Fuzhou
[13] Fujian
来源：
结构化学 | 2005年 / 09期
关键词：
D O I：
暂无
中图分类号：
O621.1 [有机化学理论、物理有机化学];
学科分类号：
摘要：
The title compound {(5:(1-[(2-MeOC6H4)C3H6]C9H6}Li(DME) (DME = 1,2-di- methoxy-ethylene) was synthesized by the treatment of 3-[(2-methoxyphenyl)-isopropyl]-indene with 1 equiv. of n-BuLi followed by the recrystallization from a mixed solution of toluene and DME. The compound crystallizes in orthorhombic system, pace group Pbca with a = 14.5677(3), b = 15.54670(10), c = 18.7498(3) , Z = 8, V = 4246.45(11) 3, Dc = 1.127 g/cm3 and ((MoK() = 0.072 mm-1. The coordination geometry can be described as a distorted tetrahedron.
引用
收藏
页码：1046 / 1048
页数：3
相关论文
共 50 条
  • [1] Synthesis and Crystal Structure of {η5:η1-[（2-Methoxyphenyl）-isopropyl]-indenyl}（dimethoxyethylene）lithium1
    冯其琴
    李一梅
    王绍武
    周双六
    盛恩宏
    黄子祥
    Chinese Journal of Structural Chemistry, 2005, (09) : 1046 - 1048
  • [2] Synthesis and crystal structure of {η5:η1-[(2-methoxyphenyl)-isopropyl]-indenyl}(dimethoxyethylene)lithium
    Feng, QQ
    Li, YM
    Wang, SW
    Zhou, SL
    Sheng, EH
    Huang, ZX
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (09) : 1046 - 1048
  • [3] 1-[1-(Hydroxyimino)ethyl]-N-(2-methoxyphenyl)cyclopropanecarboxamide
    Wang, Jun-Ling
    Meng, Shuang-Ming
    Tian, Mao-Zhong
    Feng, Feng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : 01618 - U2806
  • [4] PHARMACOLOGICAL AND CLINICAL OBSERVATIONS ON 1-(2-METHOXYPHENYL PIPERAZINE)
    PAGE, IH
    WOLFORD, RW
    CORCORAN, AC
    ARCHIVES INTERNATIONALES DE PHARMACODYNAMIE ET DE THERAPIE, 1959, 119 (1-2): : 214 - 224
  • [5] (E)-1-[(2-Methoxyphenyl)methyleneamino]-guanidinium chloride
    Sonar, Vijayakumar N.
    Neelakantan, Sundar
    Siegler, Maxime
    Crooks, Peter A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O535 - O536
  • [6] (E)-1-(2,4-Dinitrophenyl)-2-[1-(2-methoxyphenyl)ethylidene]hydrazine
    Fun, Hoong-Kun
    Nilwanna, Boonlerd
    Jansrisewangwong, Patcharaporn
    Kobkeatthawin, Thawanrat
    Chantrapromma, Suchada
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3202 - U1815
  • [7] 1-(2-Methoxyphenyl)-1H-pyrrole-2,5dione
    Sirajuddin, Muhammad
    Ali, Saqib
    Tahir, M. Nawaz
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2282 - +
  • [8] An improved route to urapidil from 1-(2-methoxyphenyl)piperazine and oxetane
    Zhang, Li-Zhi
    Liu, Feng-Liang
    Xiang, Hao-Yue
    Zhan, Zhen-Yu
    Shen, Jie
    CHEMICAL PAPERS, 2024, 78 (07) : 4395 - 4400
  • [9] Ethyl 1-(butan-2-yl)-2-(2-methoxyphenyl)-1H-benzimidazole-5-carboxylate
    Arumugam, Natarajan
    Ngah, Nurziana
    Osman, Hasnah
    Rahim, Aisyah Saad Abdul
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3231 - U1467
  • [10] 1-(2,6-Dichlorobenzoyl)-3-(2-methoxyphenyl)thiourea
    Rauf, M. Khawar
    Badshah, Amin
    Bolte, Michael
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2665 - U1316
12345