EQUILIBRIUM CONSTANT OF ADDUCTIVE REACTION BETWEEN BIS-(O, O′-DICYCLOHEXYLDITH-IOPHOSPHATO) NICKEL(Ⅱ) AND BENZYL-AMINE AND CRYSTAL STRUCTURE OF ADDUCTS Ni[(C6H11O)2PS2]2·2NH2CH2C6H5

被引：0

作者：

游效曾

徐正

徐昕

林建华

俞运鹏

林墀昌

刘世雄

机构：

[1] Fuzhou University

[2] Nanjing 210008

[3] PRC

[4] Nanjing University

[5] Institute of Structural Chemistry

[6] Fuzhou 350002

[7] Coordination Chemistry Institute

来源：

Science Bulletin | 1992年 / 08期

基金：

中国国家自然科学基金;

关键词：

dithiophosphate; equilibrium constant; crystal structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Ⅰ. INTRODUCTIONEsters of dithiophosphoric acid are a kind of excellent extractant for separating Co-Ni and Co-Mn. It was found that Co(Ⅱ) is easy to oxidize and to form the stable six-coordinated octahedral complex Co[(RO)PS] during extraction process. And it made back-extraction process very difficult. It was found that pydridine is able to cause substitute-reduction reaction with Co[(RO)PS]and to form Co[(RO)PS]·2Py. It is of

引用

页码：657 / 661

页数：5

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[1] EQUILIBRIUM-CONSTANT OF ADDUCTIVE REACTION BETWEEN BIS-(O,O'-DICYCLOHEXYLDITHIOPHOSPHATO)NICKEL(II) AND BENZYLAMINE AND CRYSTAL-STRUCTURE OF ADDUCTS NI[(C6H11O)2PS2]2.2NH2CH2C6H5
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