Detailed investigation of optimized alkali catalyzed transesterification of Jatropha oil for biodiesel production

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作者
Waqas Ahmed [1 ,2 ]
Muhammad Faizan Nazar [3 ]
Syed Danish Ali [1 ]
Usman Ali Rana [4 ]
Salah UdDin Khan [4 ]
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[1] National Centre for Physics,Quaid-i-Azam University Campus
[2] Office of Research,Innovation and Commercialization,University of Gujrat
[3] Department of Chemistry,University of Gujrat
[4] Sustainable Energy Technologies (SET) Center,College of Engineering,PO-Box ,King Saud
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The non-edible oils are believed to be one of the major feedstock for the production of biodiesel in future.In the present study,we investigated the production of Jatropha oil methyl esters(JOMEs) via alkali-catalyzed transesterification route.The biophysical characteristics of Jatropha oil were found within the optimal range in accordance with ASTM standards as a substitute diesel fuel.The chemical composition and production yield of as-synthesized biodiesel were confirmed by various analytical techniques such as FT-IR,1H NMR,13 C NMR and gas chromatography coupled with mass spectrometry.A high percentage conversion,~96.09%,of fatty acids into esters was achieved under optimized transesterification conditions with 6 :1 oil to methanol ratio and 0.9 wt% Na OH for 50 min at ~60°C.Moreover,twelve fatty acids methyl esters(FAME) were quantified in the GC/MS analysis and it was interesting to note that the mass fragmentation pattern of saturated,monounsaturated and diunsaturated FAME was comparable with the literature reported values.
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页数:6
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