Effects of Si and Ce on the microstructure and hydrogen storage property of TiCrVFeCealloy

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MI JingLIU XiaoPeng LI ZhiNianJIANG LiJunHUANG Zhuo WANG ShuMao Energy Material and Technology Research InstituteGeneral Research Institute for Nonferrous MetalsBeijing China [100088 ]
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TG139.7 [];
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In this paper,the effects of Si and Ce on the microstructure and hydrogen storage property of Ti26.5 Cr20V45Fe8.5Ce0.5 alloy were studied,respectively.First of all,effects of Si on the microstructure and hydrogen storage properties of Ti26.5Cr20(V45Fe8.5)1-xSixCe0.5(x=0,0.5,1.0,1.5 and 2.0 at%)alloys were studied by X-ray diffraction,scanning electron microscopy and P-C isotherm measurements.As the Si addition increases,the hydrogen absorption capacities of alloys decrease but the equilibrium pressure increases,due to the formation of Laves phase.Secondly,the effect of Ce on Ti26.5Cr20(V45Fe8.5)0.98Si2 alloy was studied.It was found that Ce addition is an effective way to eliminate the effect of Si on the hydrogen storage properties of the alloy.
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