A comparative study of the electrooxidation of C1 to C3 aliphatic alcohols on Ni modified graphite electrode

被引：0

作者：

JAFARIAN M ^{[1
]}

MIRZAPOOR A ^{[1
]}

DANAEE I ^{[2
]}

SHAHNAZI Sangachin AA ^{[2
]}

GOBAL F ^{[3
]}

机构：

[1] Departement of Chemistry,KNToosi University of Technology,Tehran,Iran

[2] Abadan Faculty of Petroleum Engineering,Petroleum University of Technology,Abadan,Iran

[3] Departement of Chemistry,Sharif University of

来源：

Science China(Chemistry) | 2012年 / 09期

关键词：

D O I：

暂无

中图分类号：

O646.5 [电解与电极作用];

学科分类号：

摘要：

Nickel modified graphite electrodes(G/Ni) prepared by galvanostatic deposition were examined for their redox process and electrocatalytic activities towards the oxidation of methanol,ethanol,1-propanol and 2-propanol in alkaline solutions.The methods of cyclic voltammetry(CV),chronoamperometry(CA) and impedance spectroscopy(EIS) were employed.In CV studies,the electrochemical response,peak current varied in the order of MeOH > EtOH > 1-PrOH > 2-PrOH.Under the CA regime,a higher catalytic rate constant obtained for methanol oxidation was in agreement with CV measurements.Lower charge transfer resistance was obtained for low carbon alcohols oxidation and significantly higher exchange current density was obtained for methanol oxidation.

引用

页码：1819 / 1824

页数：6

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