A Mg alloy with no hydrogen evolution during dissolution

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作者
Fuyong Cao [1 ]
Bo Xiao [1 ]
Ziming Wang [1 ]
Tao Ying [2 ]
Dajiang Zheng [1 ]
Andrej Atrens [3 ]
GuangLing Song [1 ,4 ,3 ]
机构
[1] Center for Marine Materials Corrosion and Protection, College of Materials, Xiamen University
[2] National Engineering Research Center of Light Alloy Net Forming, School of Materials Science and Engineering, Shanghai Jiao Tong University
[3] School of Mechanical and Mining Engineering, The University of Queensland
[4] State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen
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Hydrogen evolution is normally associated with the corrosion or dissolution of Mg alloys in aqueous solutions. This work studied the corrosion behavior of sputtered pure Mg, Mg82Zn18(at.%), Mg64Zn36(at.%), and pure Zn in 3.5% Na Cl solution. Mg64Zn36 had(ⅰ) an amorphous microstructure with some nano-scale grains,(ⅱ) a corrosion rate substantially lower than that of pure Mg, and(ⅲ) no hydrogen evolution during corrosion or anodic dissolution, because the positive corrosion potential retarded the cathodic hydrogen evolution. This is a new route to prevent hydrogen evolution during Mg corrosion, which has never previously been realized.
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页码:2084 / 2095
页数:12
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