HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2'/6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE)

被引：48
|
作者：
CHOTALIA, R
CONSTABLE, EC
HANNON, MJ
TOCHER, DA
机构：
[1] UNIV BASEL, INST ANORGAN CHEM, CH-4056 BASEL, SWITZERLAND
[2] UNIV CAMBRIDGE, CHEM LAB, CAMBRIDGE CTR MOLEC RECOGNIT, CAMBRIDGE CB2 1EW, ENGLAND
[3] UNIV WARWICK, DEPT CHEM, COVENTRY CV4 7AL, W MIDLANDS, ENGLAND
[4] UCL, DEPT CHEM, LONDON WC1H 0AJ, ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 22期
关键词：
D O I：
10.1039/dt9950003571
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of complexes containing hypodentate didentate 2,2':6',2 ''-tetrpyridine (terpy) ligands of general formula [Ru(L-N,N')(2)(terpy-N,N')](2+) [L = 2,2'-bipyridine (bipy) or 1,10-phenanthroline] have been prepared. The complexes [Ru(bipy-N,N')(2)(terpy-N,N')][PF6](2) and [Ru(bipy-N,N')(2)(bterpy-N,N')][PF6](2) (bterpy = 6-bromo-2,2':6'2 ''-terpyridine) have been structurally characterised and shown to contain the didentate terpy ligand in the solid state.
引用
收藏
页码：3571 / 3580
页数：10
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