Poly[tetraaqua(5-hydroxypyridin-1-ium-3-carboxylato-kappa O-3)tris(mu-oxalato-kappa O-4(1), O-2 : O-1 ', O-2 ') dieuropium(III)]

被引：1
|
作者：
Xu, Shan-Shan [1 ]
Mi, Jun-Long [1 ]
Chen, Hong-Ji [1 ]
机构：
[1] Jinan Univ, Dept Mat Sci & Engn, Jinan 510632, Shandong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813011057
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Eu2(C6H5NO 3)2(C2O4)3(H 2O)4]n, the EuIII atom is bonded to one O atom from a monodentate 5-hydroxypyridin-1-ium-3-carboxylate ligand, six O atoms from three oxalate ligands and two water molecules, exhibiting a highly distorted tricapped trigonal geometry. Three independent oxalate ligands, each lying on an inversion center, bridge the EuIII atoms, forming a brickwall-like layer parallel to (001), which is stabilized by intralayer O - H⋯O hydrogen bonds. The layers are further linked through interlayer O - H⋯O and N - H⋯O hydrogen bonds and π-π interactions between the pyridine rings [centroid-centroid distance = 3.5741 (14) Å] into a three-dimensional supramolecular network.
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页码：M294 / +
页数：9
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