IONIC LIQUID MEDIATED PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [1-METHYLIMIDAZOLIUM]2[CIS-MOO2(SALICYLATO-O(1),O(2)2]

被引：8
|
作者：
BOUTILIER, K [1 ]
MACGILLIVRAY, LR [1 ]
SUBRAMANIAN, S [1 ]
ZAWOROTKO, MJ [1 ]
机构：
[1] ST MARYS UNIV,DEPT CHEM,HALIFAX B3H 3C3,NS,CANADA
来源：
JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1993年 / 23卷 / 10期
关键词：
D O I：
10.1007/BF01247239
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complex salt, [1-MeimH]2[CiS-MoO2(sal)2], 1, (1-Meim = 1-methylimidazole, sal = o-C6H4(O-)(COO-)) has been prepared by reacting MO(CO)6 with molten 1-methyl imidazolium salicylate [1-MeimH][salH], and the structure of 1 has been determined by single crystal X-ray crystallography: triclinic, P1BAR, a = 9.220(2), b = 9.469(3), c = 15.368(4) angstrom, alpha = 105.04(4), beta = 99.48(3), gamma = 109.48(3)-degrees, Z = 2, D(calc) = 1.60 g/cm. 2809 reflections with I > 2.5sigma(I) gave a final values of R = 0.031 and R(w) = 0.041.
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页码：773 / 778
页数：6
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