PREPARATION AND CRYSTAL-STRUCTURES OF THE CROWDED TRIORGANOTIN ISOTHIOCYANATE (PHME2SI)3CSNME2NCS AND NITRATE (PHME2SI)3CSNME2ONO2

被引：16
|
作者：
ALJUAID, SS [1 ]
ALRAWI, M [1 ]
EABORN, C [1 ]
HITCHCOCK, PB [1 ]
SMITH, JD [1 ]
机构：
[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 446卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)80048-G
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crowded organotin compound (PbMe2Si)3CSnMe2NCS is monomeric in the solid-state and contains tetracoordinate tin, the first tin isothiocyanate to be shown to do so. The related nitrate (PhMe2Si)3CSnMe2ONO2 is also monomeric, but there is a weak intramolecular interaction between the tin atom and one of the oxygen atoms of the NO2 group, making the tin quasi-pentacoordinate. The weak coordination appears, however, to have no significant effect on the disposition of the four full bonds around the tin, the geometry being markedly distorted from tetrahedral by steric interactions to a similar extent in both the nitrate and the isothiocyanate.
引用
收藏
页码：161 / 166
页数：6
相关论文
共 50 条
  • [1] PREPARATION AND CRYSTAL-STRUCTURES OF THE CROWDED ORGANOTIN FLUORIDES (PHME2SI)3CSNME2F, (ME3SI)3CSNME2F, AND (ME3SI)3CSNPH2F
    ALJUAID, SS
    DHAHER, SM
    EABORN, C
    HITCHCOCK, PB
    SMITH, JD
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) : 117 - 127
  • [2] FORMATION OF A TETRAZOLE FROM (PHME2SI)3CSIME2 .1. CRYSTAL-STRUCTURE OF (PHME2SI)3CSIME3N-N=C(ME)-N=N
    ALVANIPOUR, A
    BUTTRUS, NH
    EABORN, C
    HITCHCOCK, PB
    MANSOUR, AI
    SAXENA, AK
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 349 (1-2) : 29 - 36
  • [3] Organotin compounds containing a bulky (Me3Si)3C or related ligand.: Crystal structures of {(Me3Si)3CMe(O2NO)Sn}2O, (PhMe2Si)3CSnMeCl2 and (PhMe2Si)3CSnCl3
    Al-Juaid, SS
    Al-Rawi, M
    Eaborn, C
    Hitchcock, PB
    Smith, JD
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 564 (1-2) : 215 - 226
  • [4] Geometry of SiOCN linkage. Crystal structure of (Me3Si)2(PhMe2Si)CSi-Me2OCN
    Ayoko, G. Adefikayo
    Eaborn, Colin
    Hitchcock, Peter B.
    Organometallics, 1995, 14 (10):
  • [5] THE GEOMETRY OF SIOCN AND SINCO LINKAGES - THE CRYSTAL-STRUCTURES OF (ME(3)SI)(2)(PH(2)MESI)CSIME(2)OCN AND (PHME(2)SI)(3)CSIME(2)NCO
    ALJUAID, SS
    ALNASR, AAK
    AYOKO, GA
    EABORN, C
    HITCHCOCK, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) : 155 - 160
  • [6] 1,3-migration of a phenyl group in the conversion of (Me3Si)2(PhMe2Si)CSiMePhX into (Me3Si)2(Ph2MeSi)CSiMe2Y species
    Eaborn, C
    Kowalewska, A
    Stanczyk, W
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 560 (1-2) : 41 - 46
  • [7] STRUCTURE AND DYNAMICS OF HINDERED ORGANOSILICON COMPOUNDS - THE CONFORMATIONS OF SYMMETRICAL (ME3SI)3C AND (PHME2SI)3C DERIVATIVES
    AVENT, AG
    BOTT, SG
    LADD, JA
    LICKISS, PD
    PIDCOCK, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (01) : 9 - 21
  • [8] GEOMETRY OF THE SIOCN LINKAGE - CRYSTAL-STRUCTURE OF (ME(3)SI)(2)(PHME(2)SI)CSIME(2)OCN
    AYOKO, GA
    EABORN, C
    HITCHCOCK, PB
    ORGANOMETALLICS, 1995, 14 (10) : 4960 - 4961
  • [9] COMPOSITION AND CHEMISTRY OF THE MIXED HIGHER-ORDER CUPRATES (PHME2SI)M(CH3)NCU(CN)LI(M+N)
    SINGER, RD
    OEHLSCHLAGER, AC
    JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (11): : 3510 - 3514
  • [10] Formation of unexpected selenium-rich compounds by selenation of the very bulky (PhMe2Si)3CLi:: s-Tetraselenane, a novel polyseleno heterocycle
    Klapoetke, Thomas M.
    Krumm, Burkhard
    Polborn, Kurt
    Scherr, Matthias
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (15) : 2937 - 2941
12345