BISMUTH(III) DIMETHYLDITHIOPHOSPHINATE, BI(S2PME2)3 - ANOTHER DIMER FORMED THROUGH SECONDARY BONDING - THE STEREOCHEMICALLY ACTIVE LONE-PAIR REVISITED

被引：19
|
作者：
EDELMANN, FT
NOLTEMEYER, M
HAIDUC, I
SILVESTRU, C
CEAOLIVARES, R
机构：
[1] NATL AUTONOMOUS UNIV MEXICO,INST QUIM,CIUDAD UNIV,MEXICO CITY 04510,DF,MEXICO
[2] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
来源：
POLYHEDRON | 1994年 / 13卷 / 04期
关键词：
D O I：
10.1016/S0277-5387(00)84730-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal and molecular structures of bismuth(III) dimethyl-dithiophosphinate, Bi(S2PMe2)3 were investigated by X-ray diffraction. The compound is a centrosymmetric dimer in which pentagonal-bipyramidal monomeric units are held together by secondary Bi...S interaction. The possible presence of a stereochemically active lone pair is discussed.
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收藏
页码：547 / 552
页数：6
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