SOLVENT-FREE TELOMERIZATION OF BUTADIENE WITH WATER INTO OCTADIENOLS IN THE PRESENCE OF NONIONIC SURFACTANT - EFFICIENT MICELLAR CATALYSIS

被引：20
|
作者：
MONFLIER, E
BOURDAUDUCQ, P
COUTURIER, JL
KERVENNAL, J
SUISSE, I
MORTREUX, A
机构：
[1] ELF ATOCHEM,CRRA,F-69310 PIERRE BENITE,FRANCE
[2] ENSCL,CATALYSE HETEROGENE & HOMOGENE LAB,CNRS,URA 402,F-59652 VILLENEUVE DASCQ,FRANCE
来源：
CATALYSIS LETTERS | 1995年 / 34卷 / 1-2期
关键词：
TELOMERIZATION; OCTADIENOL; BUTADIENE; NONIONIC SURFACTANT; SOLUBILIZATION; MICELLE;
D O I：
10.1007/BF00808335
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Telomerization of butadiene with water into 2,7-octadien-1-ol using a palladium-hydrosoluble phosphine system was investigated. The reaction was carried out without solvent in the presence of carbon dioxide and a nonionic surfactant. Promoted effect of neutral surfactant appeared above the critical micelle concentration and the conversion and the selectivity depended on the structure of nonionic surfactant hydrophilic part. The role of the nonionic surfactant is discussed.
引用
收藏
页码：201 / 212
页数：12
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