PHOTOCHEMICAL-REACTIONS OF COMPLEXES OF AROMATIC-AMINES WITH POLYGALOMETHANES

被引:0
|
作者
BUDYKA, MF [1 ]
ALFIMOV, MV [1 ]
机构
[1] RUSSIAN ACAD SCI,NN SEMENOV CHEM PHYS INST,MOSCOW 117977,RUSSIA
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D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The data for chemical processes occurring on light irradiation of complexes of aromatic amines with polygalomethanes are critically reviewed. It is shown that electron transfer from amine to halomethane is a main photochemical reaction of complexes. The properties and reactions of primary ion-radical particles formed and secondary intermediates are discussed. Mechanisms of photoinduced formation of triphenylmethane dyes and acridine derivatives are considered.
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页码:755 / 768
页数:14
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